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Semi-Insulating , Undoped Gallium Arsenide Substrate , 4”, Test Grade

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XIAMEN POWERWAY ADVANCED MATERIAL CO., LTD.

Semi-Insulating , Undoped Gallium Arsenide Substrate , 4”, Test Grade

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Product Details

Semi-Insulating , Undoped Gallium Arsenide Substrate , 4”, Test Grade

 

PAM-XIAMEN Develops and manufactures compound semiconductor substrates-gallium arsenide crystal and wafer. We has used advanced crystal growth technology, vertical gradient freeze(VGF) and (GaAs)Gallium Arsenide wafer processing technology. The required electrical properties are obtained by adding dopants such as silicon or zinc. The result is n-type or p-type high-resistance (>10^7 ohm.cm) or low-resistance (<10 - 2 ohm.cm) semiconductors. The wafer surfaces are generally epi-ready (extremely low contamination) i.e. their quality is suitable for direct use in epitaxial processes.

 

(GaAs)Gallium Arsenide Wafers,Semi-insulating for Microelectronics Applications

ItemSpecificationsRemarks
Conduction TypeInsulating 
Growth MethodVGF 
DopantUndoped 
Wafer Diamter4, inchIngot available
Crystal Orientation(100)+/- 0.5° 
OFEJ, US or notch 
Carrier Concentrationn/a 
Resistivity at RT>1E7 Ohm.cm 
Mobility>5000 cm2/V.sec 
Etch Pit Density<8000 /cm2 
Laser Markingupon request 
Surface FinishP/P 
Thickness350~675um 
Epitaxy ReadyYes 
PackageSingle wafer container or cassette

 

Properties of GaAs Crystal

PropertiesGaAs
Atoms/cm34.42 x 1022
Atomic Weight144.63
Breakdown Fieldapprox. 4 x 105
Crystal StructureZincblende
Density (g/cm3)5.32
Dielectric Constant13.1
Effective Density of States in the Conduction Band, Nc (cm-3)4.7 x 1017
Effective Density of States in the Valence Band, Nv (cm-3)7.0 x 1018
Electron Affinity (V)4.07
Energy Gap at 300K (eV)1.424
Intrinsic Carrier Concentration (cm-3)1.79 x 106
Intrinsic Debye Length (microns)2250
Intrinsic Resistivity (ohm-cm)108
Lattice Constant (angstroms)5.6533
Linear Coefficient of Thermal Expansion,6.86 x 10-6
ΔL/L/ΔT (1/deg C)
Melting Point (deg C)1238
Minority Carrier Lifetime (s)approx. 10-8
Mobility (Drift)8500
(cm2/V-s)
µn, electrons
Mobility (Drift)400
(cm2/V-s)
µp, holes
Optical Phonon Energy (eV)0.035
Phonon Mean Free Path (angstroms)58
Specific Heat0.35
(J/g-deg C)
Thermal Conductivity at 300 K0.46
(W/cm-degC)
Thermal Diffusivity (cm2/sec)0.24
Vapor Pressure (Pa)100 at 1050 deg C;
1 at 900 deg C

 

WavelengthIndex
(µm)
2.63.3239
2.83.3204
33.3169
3.23.3149
3.43.3129
3.63.3109
3.83.3089
43.3069
4.23.3057
4.43.3045
4.63.3034
4.83.3022
53.301
5.23.3001
5.43.2991
5.63.2982
5.83.2972
63.2963
6.23.2955
6.43.2947
6.63.2939
6.83.2931
73.2923
7.23.2914
7.43.2905
7.63.2896
7.83.2887
83.2878
8.23.2868
8.43.2859
8.63.2849
8.83.284
93.283
9.23.2818
9.43.2806
9.63.2794
9.83.2782
103.277
10.23.2761
10.43.2752
10.63.2743
10.83.2734
113.2725
11.23.2713
11.43.2701
11.63.269
11.83.2678
123.2666
12.23.2651
12.43.2635
12.63.262
12.83.2604
133.2589
13.23.2573
13.43.2557
13.63.2541

 

What is GaAs wafer?

Gallium arsenide (GaAs) is a compound of the elements gallium and arsenic. It is a III-V direct band gap semiconductor with a zinc blende crystal structure.

GaAs wafer is an important semiconducor material. It belongs to group III-V compound semiconductor. It is a sphalerite type lattice structure with a lattice constant of 5.65x 10-10m, a melting point of 1237 ℃ and a band gap of 1.4 EV. Gallium arsenide can be made into semi insulating high resistance materials with resistivity higher than silicon and germanium by more than three orders of magnitude, which can be used to make integrated circuit substrate, infrared detector, γ photon detector, etc. Because its electron mobility is 5-6 times larger than that of silicon, it has been widely used in microwave devices and high-speed digital circuits. The semiconductor device made of GaAs has the advantages of high frequency, high temperature and low temperature, low noise and strong radiation resistance. In addition, it can also be used to make bulk effect devices.

What is the Electrical propertiesof GaAs Wafer

Basic Parameters

Breakdown field≈4·105 V/cm
Mobility electrons≤8500 cm2 V-1s-1
Mobility holes≤400 cm2 V-1s-1
Diffusion coefficient electrons≤200 cm2/s
Diffusion coefficient holes≤10 cm2/s
Electron thermal velocity4.4·105 m/s
Hole thermal velocity1.8·105m/s

Mobility and Hall Effect

Electron Hall mobility versus temperature for different doping levels.

1. Bottom curve: Nd=5·1015cm-3;
2. Middle curve : Nd=1015cm-3;
3. Top curve : Nd=5·1015cm-3
For weakly doped GaAs at temperature close to 300 K, electron Hall mobility
µH=9400(300/T) cm2 V-1 s-1
Electron Hall mobility versus temperature for different doping levels and degrees of compensation (high temperatures):
Open circles: Nd=4Na=1.2·1017 cm-3;
Open squares: Nd=4Na=1016 cm-3;
Open triangles: Nd=3Na=2·1015 cm-3;
Solid curve represents the calculation for pure GaAs
For weakly doped GaAs at temperature close to 300 K, electron drift mobility
µn=8000(300/T)2/3 cm2 V-1 s-1
Drift and Hall mobility versus electron concentration for different degrees of compensation T= 77 K
 
Drift and Hall mobility versus electron concentration for different degrees of compensation T= 300 K
 

Approximate formula for the Hall mobility

. µn =µOH/(1+Nd·10-17)1/2, where µOH≈9400 (cm2 V-1 s-1), Nd- in cm-3
.

Temperature dependence of the Hall factor for pure n-type GaAs in a weak magnetic field
Temperature dependence of the Hall mobility for three high-purity samples

For GaAs at temperatures close to 300 K, hole Hall mobility

 (cm2V-1s-1), (p - in cm-3)
For weakly doped GaAs at temperature close to 300 K, Hall mobility
µpH=400(300/T)2.3 (cm2 V-1 s-1).

The hole Hall mobility versus hole density.


rH=1.25.At T= 300 K, the Hall factor in pure GaAs

Transport Properties in High Electric Fields

Field dependences of the electron drift velocity.

Solid curve was calculated by
Dashed and dotted curves are measured data, 300 K
Field dependences of the electron drift velocity for high electric fields, 300 K.
 
Field dependences of the electron drift velocity at different temperatures.
 
Fraction of electrons in L and X valleys. nL and nX as a function of electric field F at 77, 160, and 300 K, Nd=0
Dotted curve - L valleys, dashed curve - X valleys.
Mean energy E in Γ, L, and X valleys as a function of electric field F at 77, 160, and 300 K, Nd=0
Solid curve - Γ valleys, dotted curve - L valleys, dashed curve - X valleys.
Frequency dependences of electron differential mobility.
µd is real part of the differential mobility; µd*is imaginary part of differential mobility.
F= 5.5 kV cm-1
 
The field dependence of longitudinal electron diffusion coefficient D||F.
Solid curves 1 and 2 are theoretical calculations. Dashed curves 3, 4, and 5 are experimental data.
Curve 1 - from
Curve 2 - from
Curve 3 - from
Curve 4 - from
Curve 5 -
Field dependences of the hole drift velocity at different temperatures.
 
Temperature dependence of the saturation hole velocity in high electric fields
 
The field dependence of the hole diffusion coefficient.
 

Impact Ionization

There are two schools of thought regarding the impact ionization in GaAs.

The first one states that impact ionization rates αi and βi for electrons and holes in GaAs are known accurately enough to distinguish such subtle details such as the anisothropy of αi and βi for different crystallographic directions. This approach is described in detail in the work by Dmitriev et al.[1987].

Experimental curves αi and βi versus 1/F for GaAs.
Experimental curves αi and βi versus 1/F for GaAs.
Experimental curves αi and βi versus 1/F for GaAs.

The second school focuses on the values of αi and βi for the same electric field reported by different researches differ by an order of magnitude or more. This point of view is explained by Kyuregyan and Yurkov [1989]. According to this approach we can assume that αi = βi. Approximate formula for the field dependence of ionization rates:
αi = β i =αoexp[δ - (δ2 + (F0 / F)2)1/2]
where αo = 0.245·106 cm-1; β = 57.6 Fo = 6.65·106 V cm-1 (Kyuregyan and Yurkov [1989]).

Breakdown voltage and breakdown field versus doping density for an abrupt p-n junction.

Recombination Parameter

Pure n-type material (no ~ 1014cm-3) 
The longest lifetime of holesτp ~3·10-6 s
Diffusion length Lp = (Dp·τp)1/2Lp ~30-50 µm.
Pure p-type material 
(a)Low injection level 
The longest lifetime of electronsτn ~ 5·10-9 s
Diffusion length Ln = (Dn·τ n)1/2Ln ~10 µm
(b) High injection level (filled traps) 
The longest lifetime of electronsτ ~2.5·10-7 s
Diffusion length LnLn ~ 70 µm

 

Surface recombination velocity versus doping density

Different experimental points correspond to different surface treatment methods.

Radiative recombination coefficient

90 K1.8·10-8cm3/s
185 K1.9·10-9cm3/s
300 K7.2·10-10cm3/s

Auger coefficient

300 K~10-30cm6/s
500 K~10-29cm6/s

 

Are You Looking for GaAs Wafer?

PAM-XIAMEN is your go-to place for everything wafers, including GaAs wafers, as we have been doing it for almost 30 years! Enquire us today to learn more about the wafers that we offer and how we can help you with your next project. Our group team is looking forward to providing both quality products and excellent service for you!

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