4j29 Kovar Iron Nickel Cobalt Alloy Pipe Low Resistance Square / Round Tube Pipe

4j29 Kovar Iron Nickel Cobalt Alloy Pipe Low Resistance Square / Round Tube Pipe

General Description:

4J29, is a nickel-cobalt ferrous alloy compositionally identical to Fernico 1, designed to have substantially the same thermal expansion characteristics as borosilicate glass (~5 × 10⁻⁶ /K between 30 and 200 °C, to ~10 × 10⁻⁶ /K at 800 °C) in order to allow a tight mechanical joint between the two materials over a range of temperatures. It finds application in glass-to-metal seals in scientific apparatus, and conductors entering glass envelopes of electronic parts such as vacuum tubes (valves), X-ray and microwave tubes and some lightbulbs.

Kovar not only has thermal expansion similar to glass, but its nonlinear thermal expansion curve can often be made to match a glass, thus allowing the joint to tolerate a wide temperature range. Chemically, it bonds to glass via the intermediate oxide layer of nickel(II) oxide and cobalt(II) oxide; the proportion of iron oxide is low due to its reduction with cobalt. The bond strength is highly dependent on the oxide layer thickness and character. The presence of cobalt makes the oxide layer easier to melt and dissolve in the molten glass. A grey, grey-blue or grey-brown color indicates a good seal. A metallic color indicates lack of oxide, while black color indicates overly oxidized metal, in both cases leading to a weak joint.

4J29was invented to meet the need for a reliable glass-to-metal seal, which is required in electronic devices such as light bulbs, vacuum tubes, cathode ray tubes, and in vacuum systems in chemistry and other scientific research. Most metals cannot seal to glass because their coefficient of thermal expansion is not the same as glass, so as the joint cools after fabrication the stresses due to the differential expansion rates of the glass and metal cause the joint to crack.

Chemical Composition:

Main properties:

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